Mexico stumbled into the final phase of North, Central America and Caribbean qualifying, while Trinidad and Tobago advanced from Group 1.
Despite the passionate cupport of a 15,000-strong crowd, hosts Chile were defeated 2-0 by a tactically astute England side in Coquimbo.
David Villa's penalty, a cool finish by Fernando Torres and Santi Cazorla's deflected strike gave Spain a 3-0 win over Chile on Wednesday.